Product ID:CALCIUM HYPOCHLORITE GRANULAR
MSDS Date:04/14/1989
FSC:6810
NIIN:00-242-4770
MSDS Number: BKBBN

OLIN CORPORATION

120 LONG RIDGE ROAD
STAMFORD, CT 06904
US

Emergency Phone: 203-356-3449/800-OLIN-911

Info Phone: 203-356-3449

Cage: 0G578

OLIN CORPORATION

STAMFORD, CT 06904-1355 US

Telephone: 203-356-3449

Cage: 0G578

CALCIUM HYPOCHLORITE (SARA III)

CAS: 7778-54-3

RTECS: NH3485000

Fraction By Weight: 65-75%

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

SODIUM CHLORIDE

CAS: 7647-14-5

RTECS: VZ4725000

Fraction By Weight: 10-20%

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 5.5-10%

CALCIUM CHLORATE

CAS: 10137-74-3

RTECS: FN9800000

Fraction By Weight: 0-5%

CALCIUM CHLORIDE

CAS: 10043-52-4

RTECS: EV9800000

Fraction By Weight: 0-5%

CALCIUM HYDROXIDE

CAS: 1305-62-0

RTECS: EW2800000

Fraction By Weight: 0-4%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 5 MG/M3; 9293

LD50 LC50 Mixture:ORL LD50:850MG/KG(RAT)DERMAL>2G/KG(RAB)*
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION EXPOSURE MAY CAUSE
IMPAIRMENT OF LUNG FUNCTIONS AND PERMANENT LUNG DAMAGE. IT MAY
CAUSE BURNS TO THE RESPIRATORY TRACT WITH THE PRODUCTION OF LUNG
EDEMA.EXPO MAY CAUSE DESTRUCTION OF THE DE RMIS WITH IMPAIRMENT OF
THE SKIN AT SITE OF CONTACT TO REGENERATE.
Explanation of Carcinogenicity:THIS PRODUCT IS NOT KNOWN OR REPORTED TO
BE CARCINOGENIC BY ANY REFERENCE SOURCE INCLUDING IARC, OSHA, NTP
OR EPA.
Effects of Overexposure:INHALED:IRRIT TO
NOSE,MOUTH,THROAT,LUNGS.SHORTNESS OF BREATH,WHEEZING,CHOKING,CHEST
PAINS.EYE:IRRIT/BURNS.MAY IMPAIR
VISION/CORNEAL.SKIN:IRRIT/BURNS.REDNESS,SWELLING/SCAB
FORMATION.INGESTED:IRRIT/BURN TO GASTROINTEST TRACT,INCLUDING
STOMACH & INTESTINES.NAUSEA,VOMITING,DIARRHEA,ABDOMINAL
PAIN,BLEEDING/TISSUE ULCERATION
Medical Cond Aggravated by Exposure:ASTHMA, RESPIRATORY AND
CARDIOVASCULAR DISEASE. *INHALATION LC50 APPROX 1700 MG/M3/HR
(RAT); AQUATIC LC50=0.088 MG/L (BLUEGILL).

First Aid:EYES:IMMED FLUSH W/LOTS OF H2O FOR 15 MIN,OCCASION LIFTING
UPPER/LOWER EYELIDS.CALL DOCTOR.SKIN:IMMED FLUSH W/H2O FOR 15
MIN.CALL DOCTOR.IF CLOTHES COME IN CONTACT W/PRODUCT,REMOVE
IMMED/WASH BEFORE R EUSE.INGESTION:DRINK LOTS OF H2O.DO NOTINDUCE
VOMITING.CALL DOCTOR.DO NOT GIVE ANYTHING BY MOUTH IF PERSON IS
UNCONSCIOUS/HAVING CONVULSION.INHALED:MOVE TO FRESH AIR.SUPPORT
RSPRTN IF NEEDED.CALL DOC

Extinguishing Media:N/K *PH:10.5-11.5 (1% SOLUTION)
Fire Fighting Procedures:USE WATER TO COOL CONTAINTERS EXPOSED TO FIRE.
DO NOT USE DRY EXTINGUISHERS CONTAINING AMMONIUM COMPOUNDS.

Spill Release Procedures:CONTAIN ALL VIRGIN MATERIAL IN A CLEAN DRY
CONTAINER USING CLEAN DEDICATED EQUIPMENT TO CLEAN UP
MATERIAL.CONTAIN ALL CONTAMINATED MATERIAL IN A CLEAN DRY CONTAINER
AND REMOVE TO A WELL VENTILATED ARE A BEING SURE TO NOT SEAL
TIGHTLY.

Handling and Storage Precautions:KEEP TIGHTLY SEALED. STORE IN A COOL,
DRY, WELL VENTILATED AREA. DO NOT STORE AT TEMPERATURES ABOVE 52 C.
Other Precautions:DO NOT TAKE INTERNALLY, AVOID CONTACT WITH EYES, SKIN
OR COTHING, UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH WATER.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE LOCAL EXHAUST VENTILATION TO MINIMIZE DUST AND CHLORINE
LEVELS.
Protective Gloves:NEOPRENE OR PVC GLOVES.
Eye Protection:CHEMICAL GOGGLES
Other Protective Equipment:NEOPRENE OR PVC BOOTS, APRONS OR IMPERMEABLE
SUIT TO AVOID SKIN CONTACT.
Supplemental Safety and Health

HCC:D1
Decomp Temp:Decomp Text:350F/177C
pH:*
Solubility in Water:APPROX 18% @ 25C
Appearance and Odor:WHITE FREE FLOWING POWDER WITH CHLORINE-LIKE ODOR

ACIDS,ORGANICS,NITROGEN CONTAINING CMPDS,DRY POWDER FIRE EXT,(CONTAINS
MONO-AMMONIUM PHOSPHATE)CORROSIVE FLAM/COMBUS MAT
Stability Condition to Avoid:TEMPERATURES ABOVE 177 DEG C.
Hazardous Decomposition Products:CHLORINE GAS

Waste Disposal Methods:IF THIS PRODUCT BECOMES A WASTE, IT MEETS THE
CRITERIA OF HAZARDOUS WASTE DOO1. IT MUST BE DISPOSED OF IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS IN A PERMITTED
HAZARDOUS WASTE TREATMENT, STORAGE AND DISPOSAL FACILITY BY
TREATMENT.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.